How does strength of boric acid solution increase in presence of salicylic acid?
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited Apr 6 at 7:15
andselisk
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
$endgroup$
add a comment |
$begingroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited Apr 6 at 7:15
andselisk
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
$endgroup$
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02
add a comment |
$begingroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
edited Apr 6 at 7:15
andselisk
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
$endgroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
inorganic-chemistry acid-base
edited Apr 6 at 7:15
andselisk
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
edited Apr 6 at 7:15
andselisk
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
edited Apr 6 at 7:15
andselisk
19.1k661125
edited Apr 6 at 7:15
andselisk
19.1k661125
edited Apr 6 at 7:15
andselisk
19.1k661125
19.1k661125
asked Apr 6 at 4:27
RicheekRicheek
584
asked Apr 6 at 4:27
RicheekRicheek
584
asked Apr 6 at 4:27
RicheekRicheek
584
584
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02
add a comment |
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02
add a comment |
2 Answers
2
active
oldest
votes
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered Apr 6 at 5:07
PoutnikPoutnik
95229
$endgroup$
add a comment |
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2 Answers
2
active
oldest
votes
2 Answers
2
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
$endgroup$
add a comment |
$begingroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
$endgroup$
Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: Queen, A. The kinetics of the reaction of boric acid with salicylic acid. Can. J. Chem. 1977, 55 (16), 3035–3039 DOI: 10.1139/v77-421.
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
edited Apr 7 at 2:17
Gaurang Tandon
5,34362764
5,34362764
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
answered Apr 6 at 5:08
William R. EbenezerWilliam R. Ebenezer
78315
78315
add a comment |
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered Apr 6 at 5:07
PoutnikPoutnik
95229
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered Apr 6 at 5:07
PoutnikPoutnik
95229
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered Apr 6 at 5:07
PoutnikPoutnik
95229
$endgroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered Apr 6 at 5:07
PoutnikPoutnik
95229
answered Apr 6 at 5:07
PoutnikPoutnik
95229
answered Apr 6 at 5:07
PoutnikPoutnik
95229
answered Apr 6 at 5:07
PoutnikPoutnik
95229
95229
add a comment |
add a comment |
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$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
Apr 6 at 5:02